Recycling of waste metals

Secondary metals are those that are recovered from scraps, slimes, dusts, slags and waste materials. Generally the recovery of metals from waste materials require far less energy than that required for production from the primary ore. Some metals are produced only through recycling method and called as By Product such as Se, Te, Cd and Bi.

The reasons of using recycling methods are:

Recycling need less energy (table 1)

Metal Primary from ore(106 kcal/ton) Recycling(106kcal/ton)
Mg 90.2 3
Al 61.5 3
Ni 36.3 3.8
Cu 28.2 4.3
Zn 16.4 4.3
Steel 8.1 3.3
Pb 6.8 3

Copper

Recycling is a major source of copper in the industries. The copper scrap originates from foundries, fabricators and user industries. The scrap dealers sort out the scrap according to the grade and composition. The wire and cable manufacturers have their own facility or remelting facilities. Normally, a rotary type furnace that is 5-7m in length and 3m in diameter is used to melt and cast the copper for rerolling to wire rods. Figure 1 is shown for the recovery of low grade scrap copper.

Aluminium

Scrape aluminium is a major source in the industries for example: Turnings, borings, trimmings, foils and cans, these called new scraps and it doesn't need a beneficiation process. These are cut with special and is melted In a rotary furnace at about 600 oC .A melted salt is used in this process such as: flurried flaxes:AlF3,NaF,KCl,NaCl,Na3AlF6.This salt protect the molten metal against air and humety.

The percentage of salts can be as follow:

The impurities are removed through Segregation process as Al3Fe, boride and etc. Mg is removed through Cl2 gas as MgCl2.

Iron

There are two sorts of scrap iron: